New Way of Direct Nitrogen Atom Phenylation in Quinoline Derivatives

نویسندگان

  • Nadezhda E. Shchepina
  • Viktor V. Avrorin
  • Gennady A. Badun
  • Scott B. Lewis
  • Sergey N. Shurov
چکیده

Comparison of ion-molecular reactions of free-phenyl cations generated by tritium β -decay with 2-methyl- and 2-phenylquinolines has been investigated. The reaction of direct nitrogen atom phenylation with the help of nucleogenic phenyl cations has been fulfilled for the first time and a new one-step synthesis of tritium-labeled N-phenyl-2-phenylquinolinium salt-lipophilic radioactive biological marker has been elaborated.

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عنوان ژورنال:

دوره 2012  شماره 

صفحات  -

تاریخ انتشار 2012